Carbon and Its CompoundsClass 10 Chemistry NCERT Solutions
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Solution 1 of 15
Q1E X E R C I S E S
Ethane, with the molecular formula has
(a)
6 covalent bonds.
(b)
7 covalent bonds.
(c)
8 covalent bonds.
(d)
9 covalent bonds.
Solution
The correct answer is (b) 7 covalent bonds.
Explanation:
The structure of ethane () is:
CC
To determine the number of covalent bonds, we count all the single bonds between the atoms:
- There is one single covalent bond between the two carbon atoms (C-C).
- There are six single covalent bonds between the carbon and hydrogen atoms (C-H).
Total number of covalent bonds = 1 (C-C bond) + 6 (C-H bonds) = 7 covalent bonds.
Q2E X E R C I S E S
Butanone is a four-carbon compound with the functional group
(a)
carboxylic acid.
(b)
aldehyde.
(c)
ketone.
(d)
alcohol.
Solution
The correct answer is (c) ketone.
Explanation:
- The prefix "but-" indicates that the compound has a chain of four carbon atoms.
- The suffix "-one" is used to denote the presence of a ketone functional group ().
Therefore, butanone is a four-carbon compound containing a ketone functional group.
Q3E X E R C I S E S
While cooking, if the bottom of the vessel is getting blackened on the outside, it means that
(a)
the food is not cooked completely.
(b)
the fuel is not burning completely.
(c)
the fuel is wet.
(d)
the fuel is burning completely.
Solution
The correct answer is (b) the fuel is not burning completely.
Explanation:
When a fuel burns in an insufficient supply of oxygen (air), it undergoes incomplete combustion. This process produces soot, which is essentially unburnt carbon. This black soot gets deposited on the bottom of the cooking vessel, making it black. A clean, blue flame indicates complete combustion, while a yellow, sooty flame indicates incomplete combustion.
Q4E X E R C I S E S
Explain the nature of the covalent bond using the bond formation in .
Solution
A covalent bond is a chemical bond formed by the mutual sharing of electrons between atoms to achieve a stable electron configuration, similar to that of a noble gas.
In the formation of chloromethane ():
-
Valence Electrons:
- Carbon (C) has 4 valence electrons.
- Each Hydrogen (H) atom has 1 valence electron.
- Chlorine (Cl) has 7 valence electrons.
-
Electron Sharing:
- The carbon atom needs four more electrons to complete its octet.
- Each of the three hydrogen atoms needs one more electron to complete its duet.
- The chlorine atom needs one more electron to complete its octet.
-
Bond Formation:
- The carbon atom shares one of its valence electrons with each of the three hydrogen atoms, forming three single C-H covalent bonds.
- The carbon atom then shares its fourth valence electron with one of the valence electrons of the chlorine atom, forming a single C-Cl covalent bond.
- Through this sharing, carbon completes its octet (8 valence electrons), each hydrogen completes its duet (2 valence electrons), and chlorine completes its octet (8 valence electrons).
Electron Dot Structure of :
This structure shows how the sharing of electrons results in the formation of stable covalent bonds, holding the atoms together in the molecule.
Q5E X E R C I S E S
Draw the electron dot structures for
(a)
ethanoic acid.
(b)
.
(c)
propanone.
(d)
.
Solution
(a) Ethanoic acid ():
CC(=O)O
Electron Dot Structure:
** (b) Hydrogen Sulphide ():**
S
Electron Dot Structure:
** (c) Propanone ():**
CC(C)=O
Electron Dot Structure:
** (d) Fluorine molecule ():**
FF
Electron Dot Structure:
Q6E X E R C I S E S
What is an homologous series? Explain with an example.
Solution
A homologous series is a series of organic compounds that have the same functional group and similar chemical properties. The successive members of the series differ from each other by a group.
Characteristics of a homologous series:
- All members can be represented by the same general formula.
- Each successive member differs from the next by a group.
- The difference in molecular mass between any two successive members is 14 u.
- All members have the same functional group, which gives them similar chemical properties.
- There is a gradual change in physical properties (like melting point, boiling point, and density) as the molecular mass increases down the series.
Example: The homologous series of alcohols
The general formula for this series is .
- Methanol ()
- Ethanol ()
- Propanol ()
- Butanol ()
In this series, each compound has the alcohol functional group (-OH) and each successive compound differs by a unit.
Q7E X E R C I S E S
How can ethanol and ethanoic acid be differentiated on the basis of their physical and chemical properties?
Solution
Ethanol and ethanoic acid can be differentiated based on the following properties:
Physical Properties:
| Property | Ethanol () | Ethanoic Acid () |
|---|---|---|
| Smell | Pleasant, characteristic alcoholic smell. | Pungent, vinegar-like smell. |
| Taste | Burning taste. | Sour taste. |
| Melting Point | 156 K (very low). | 290 K (freezes in cold climates). |
Chemical Properties (Tests):
| Test | Ethanol | Ethanoic Acid |
|---|---|---|
| Litmus Test | No change in the colour of litmus paper (neutral). | Turns blue litmus paper red (acidic). |
| Reaction with Sodium Carbonate/Bicarbonate | No reaction. | Produces brisk effervescence due to the evolution of carbon dioxide () gas. |
| Reaction with alkaline | On warming, the purple colour of potassium permanganate is discharged as ethanol is oxidized. | No change in the colour of potassium permanganate. |
Q8E X E R C I S E S
Why does micelle formation take place when soap is added to water? Will a micelle be formed in other solvents such as ethanol also?
Solution
Micelle Formation in Water:
Micelle formation occurs when soap is dissolved in water due to the unique structure of soap molecules. A soap molecule has two distinct parts:
- A long hydrocarbon chain: This part is hydrophobic (water-repelling) and lipophilic (oil-attracting).
- An ionic end (e.g., ): This part is hydrophilic (water-attracting).
When soap is added to water, the hydrophilic heads are attracted to the water molecules, while the hydrophobic tails are repelled by them. To minimize this repulsion, the hydrophobic tails cluster together at the core, away from the water. The hydrophilic heads arrange themselves on the outer surface, facing the water. This spherical aggregation of soap molecules is called a micelle.
Micelle Formation in Ethanol:
No, a micelle will not be formed if soap is added to a solvent like ethanol. This is because ethanol is an organic solvent, and the hydrophobic hydrocarbon tail of the soap molecule is soluble in it. Since the tail is not repelled by the solvent, there is no driving force for the molecules to aggregate into a micelle structure. The soap molecules will simply dissolve in ethanol.
Q9E X E R C I S E S
Why are carbon and its compounds used as fuels for most applications?
Solution
Carbon and its compounds are widely used as fuels for several reasons:
-
High Calorific Value: Most carbon compounds, especially hydrocarbons like those in LPG, petrol, and diesel, release a large amount of heat energy per unit of mass when they undergo combustion. This makes them efficient sources of energy.
-
Abundance: Carbon-based fuels such as coal, petroleum, and natural gas are found in abundance in nature, making them readily available and relatively inexpensive.
-
Controlled Combustion: The combustion of these fuels can be easily started, controlled, and stopped. This allows for a steady and manageable release of energy, which is essential for applications like cooking, heating, and running engines.
-
Moderate Ignition Temperature: These fuels have ignition temperatures that are neither too high nor too low. This makes them safe to store and transport, but they can still be ignited easily when required.
For these reasons, carbon and its compounds are the primary sources of energy for domestic and industrial purposes.
Q10E X E R C I S E S
Explain the formation of scum when hard water is treated with soap.
Solution
Hard water contains dissolved salts of calcium () and magnesium () ions.
Soap consists of sodium or potassium salts of long-chain carboxylic acids (fatty acids). For example, sodium stearate ().
When soap is added to hard water, a chemical reaction occurs where the calcium and magnesium ions present in the water displace the sodium or potassium ions from the soap molecules. This results in the formation of insoluble calcium and magnesium salts of the fatty acids. This insoluble, curdy precipitate is called scum.
For example, the reaction with calcium ions is:
(Soap) + (Calcium ions in hard water) (Calcium stearate - Scum) + (Sodium ions)
Scum interferes with the cleaning action of soap because a significant amount of soap is wasted in reacting with the hard water ions before it can begin to form lather and clean.
Q11E X E R C I S E S
What change will you observe if you test soap with litmus paper (red and blue)?
Solution
Soaps are salts of a strong base (like NaOH or KOH) and a weak acid (a long-chain carboxylic acid).
When soap is dissolved in water, it undergoes hydrolysis, which produces a small amount of hydroxide ions (), making the solution slightly alkaline or basic.
Because the soap solution is basic:
- It will turn red litmus paper blue.
- It will have no effect on blue litmus paper.
Q12E X E R C I S E S
What is hydrogenation? What is its industrial application?
Solution
Hydrogenation:
Hydrogenation is a chemical reaction that involves the addition of hydrogen () across a double or triple bond in an unsaturated organic compound. This reaction is typically carried out in the presence of a metal catalyst, such as nickel (Ni), palladium (Pd), or platinum (Pt). The process converts unsaturated hydrocarbons (alkenes and alkynes) into saturated hydrocarbons (alkanes).
Reaction Example:
(Ethene - Unsaturated) (Ethane - Saturated)
Industrial Application:
The most significant industrial application of hydrogenation is the hardening of vegetable oils to produce solid or semi-solid fats like vanaspati ghee or margarine. Vegetable oils are liquids at room temperature because they contain unsaturated fatty acids (with double bonds). Hydrogenation converts these double bonds into single bonds, raising the melting point of the oil and turning it into a solid or semi-solid fat, which is more stable and has a longer shelf life.
Q13E X E R C I S E S
Which of the following hydrocarbons undergo addition reactions: and .
Solution
Addition reactions are characteristic of unsaturated hydrocarbons, which are compounds containing double or triple bonds between carbon atoms (alkenes and alkynes).
Let us analyze the given hydrocarbons:
- (Ethane): Follows the general formula . It is an alkane (saturated).
- (Propane): Follows the general formula . It is an alkane (saturated).
- (Propene): Follows the general formula . It is an alkene (unsaturated) and has a double bond.
- (Ethyne): Follows the general formula . It is an alkyne (unsaturated) and has a triple bond.
- (Methane): Follows the general formula . It is an alkane (saturated).
Saturated hydrocarbons (alkanes) undergo substitution reactions, not addition reactions.
Therefore, the hydrocarbons that will undergo addition reactions are the unsaturated ones: and .
Q14E X E R C I S E S
Give a test that can be used to differentiate between saturated and unsaturated hydrocarbons.
Solution
A common test to differentiate between saturated and unsaturated hydrocarbons is the Bromine Water Test.
Procedure:
- Take two test tubes, one containing the saturated hydrocarbon (e.g., hexane) and the other containing the unsaturated hydrocarbon (e.g., hexene).
- Add a few drops of bromine water (which has a reddish-brown colour) to each test tube.
- Shake both test tubes well.
Observations:
- With Unsaturated Hydrocarbon: The reddish-brown colour of the bromine water will disappear (the solution becomes colourless). This happens because the bromine undergoes an addition reaction across the double or triple bond.
- With Saturated Hydrocarbon: There will be no reaction, and the reddish-brown colour of the bromine water will persist.
This test provides a clear visual distinction between saturated and unsaturated hydrocarbons.
Q15E X E R C I S E S
Explain the mechanism of the cleaning action of soaps.
Solution
The cleaning action of soap is based on the unique structure of its molecules, which allows them to act as an emulsifying agent between oil and water.
-
Structure of a Soap Molecule: A soap molecule has two parts:
- A hydrophobic tail: A long hydrocarbon chain that is repelled by water but attracted to oil, grease, and dirt.
- A hydrophilic head: An ionic part (e.g., ) that is attracted to water.
-
Micelle Formation: When soap is dissolved in water and applied to a dirty (oily) cloth, the soap molecules orient themselves in a specific way. The hydrophobic tails embed themselves in the oily dirt particle, while the hydrophilic heads remain on the outside, pointing towards the water. This forms a spherical cluster called a micelle, with the oil droplet trapped in its core.
-
Emulsification and Removal: The outer surface of the micelle is covered with negatively charged hydrophilic heads. This causes repulsion between different micelles, preventing them from clumping together and allowing them to remain suspended in the water. This suspension of oil in water is called an emulsion.
-
Washing Away: Mechanical action, such as scrubbing or agitation in a washing machine, helps break the dirt into smaller particles and aids in micelle formation. When the cloth is rinsed with water, these micelles, containing the trapped dirt, are washed away, leaving the cloth clean.