Key Points

Atomic Foundations of Matter
16 Sections
  • 1
    Law of Conservation of Mass

    In any chemical reaction, mass is conserved, meaning it is neither created nor destroyed. The total mass of the reactants always equals the total mass of the products.

  • 2
    Law of Constant Proportions

    A chemical compound always contains the same elements combined in a fixed ratio by mass, regardless of its source. For example, water (H2OH_2O) always has a hydrogen to oxygen mass ratio of 1:8.

  • 3
    Dalton's Atomic Theory

    John Dalton proposed that all matter is made of tiny, indivisible particles called atoms. He stated that atoms of a given element are identical and that they rearrange, but are not created or destroyed, in chemical reactions.

  • 4
    Atoms and Molecules

    An atom is the smallest particle of an element. A molecule is an electrically neutral group of two or more atoms chemically bonded together that can exist independently and retains the properties of the substance.

  • 5
    Covalent Bonds by Sharing Electrons

    A covalent bond is formed when two atoms share one or more pairs of electrons to achieve a stable electron configuration. This type of bond is common between non-metal atoms.

  • 6
    Types of Covalent Bonds

    Bonds can be single (one shared pair, e.g., HHH-H in H2H_2), double (two shared pairs, e.g., O=OO=O in O2O_2), or triple (three shared pairs, e.g., in N2N_2).

  • 7
    Ionic Bonds by Transferring Electrons

    An ionic bond forms from the electrostatic attraction between oppositely charged ions, which are created by the complete transfer of one or more electrons from a metal to a non-metal.

  • 8
    Cations and Anions

    Cations are positively charged ions formed when an atom loses electrons (e.g., sodium ion, Na+Na^+). Anions are negatively charged ions formed when an atom gains electrons (e.g., chloride ion, ClCl^-).

  • 9
    Writing Chemical Formulae

    The chemical formula of a compound is determined using the 'criss-cross' method with the valencies of the elements or charges of the ions. For example, for calcium (Ca2+Ca^{2+}) and chloride (ClCl^-), the formula is CaCl2CaCl_2.

  • 10
    Polyatomic Ions

    Polyatomic ions are charged groups of covalently bonded atoms, such as sulfate (SO42SO_4^{2-}) or ammonium (NH4+NH_4^+). Use parentheses in formulas if more than one is present, for example, Ca(NO3)2Ca(NO_3)_2.

  • 11
    Naming Covalent Compounds

    To name binary covalent compounds, use prefixes (mono-, di-, tri-, etc.) to indicate the number of atoms. The second element's name ends in '-ide'. For example, CO2CO_2 is carbon dioxide.

  • 12
    Naming Ionic Compounds

    To name ionic compounds, state the cation (metal) name first, followed by the anion (non-metal) name. The anion's name typically ends in '-ide'. For example, NaClNaCl is sodium chloride.

  • 13
    Properties of Ionic Compounds

    Ionic compounds generally have high melting points, are soluble in water, and conduct electricity only when molten or dissolved in water, as their ions are then free to move.

  • 14
    Properties of Covalent Compounds

    Covalent compounds typically have low melting and boiling points, are often insoluble in water, and do not conduct electricity because they do not contain free-moving charged particles.

  • 15
    Molecular Mass

    The molecular mass of a covalent substance is the sum of the atomic masses of all atoms in one molecule. For water (H2OH_2O), the molecular mass is (2×1 u)+(1×16 u)=18 u(2 \times 1 \text{ u}) + (1 \times 16 \text{ u}) = 18 \text{ u}.

  • 16
    Formula Unit Mass

    Formula unit mass is used for ionic compounds and is the sum of the atomic masses of all atoms in a formula unit. For sodium chloride (NaClNaCl), it is (1×23 u)+(1×35.5 u)=58.5 u(1 \times 23 \text{ u}) + (1 \times 35.5 \text{ u}) = 58.5 \text{ u}.

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